Solubilised bright blue-emitting iridium complexes for solution processed OLEDs
نویسندگان
چکیده
Combining a sterically bulky, electron-deficient 2-(2,4-difluorophenyl)-4-(2,4,6-trimethylphenyl)pyridine (dFMesppy) cyclometalating C4N ligand with an electron rich, highly rigidified 1,10-(a,a0-o-xylylene)-2,20biimidazole (o-xylbiim) N4N ligand gives an iridium complex, [Ir(dFMesppy)2(o-xylbiim)](PF6), that achieves extraordinarily bright blue emission (FPL = 90%; lmax = 459 nm in MeCN) for a cationic iridium complex. This complex is compared with two reference complexes bearing 4,40-di-tert-butyl-2,20-bipyridine, and solutionprocessed organic light emitting diodes (OLEDs) have been fabricated from these materials.
منابع مشابه
Solubilised bright blue-emitting iridium complexes for solution processed OLEDs† †Electronic supplementary information (ESI) available: Synthesis CIF of the crystal structures. CCDC 1440897–1440899. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6tc00151c Click here for additional data file. Click here for additional data file.
Combining a sterically bulky, electron-deficient 2-(2,4-difluorophenyl)-4-(2,4,6-trimethylphenyl)pyridine (dFMesppy) cyclometalating C∧N ligand with an electron rich, highly rigidified 1,1'-(α,α'-o-xylylene)-2,2'-biimidazole (o-xylbiim) N∧N ligand gives an iridium complex, [Ir(dFMesppy)2(o-xylbiim)](PF6), that achieves extraordinarily bright blue emission (ΦPL = 90%; λmax = 459 nm in MeCN) for ...
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